Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene.
نویسندگان
چکیده
The synthesis and characterization of a stable 1,2-bis(ferrocenyl)diphosphene, wherein a P=P π-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d-π electron system containing a heavier pnictogen π-spacer group. Stabilization of the highly reactive P=P π-bond was achieved by steric protection using two bulky ferrocenyl moieties.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 68 شماره
صفحات -
تاریخ انتشار 2012